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排序方式: 共有711条查询结果,搜索用时 125 毫秒
1.
利用热丝化学气相沉积法(HFCVD)在碳化硅基底上制备金刚石薄膜,采用场发射扫描电子显微镜、拉曼光谱仪、原子力显微镜研究了在不同甲烷浓度条件下制备的金刚石薄膜表面形貌及物相组成,在干摩擦条件下通过往复式摩擦磨损实验测试并计算了已制备金刚石薄膜的摩擦系数和磨损率,结合物相分析及摩擦磨损实验结果分析了甲烷浓度的改变对金刚石薄膜摩擦磨损性能的影响。结果表明,由于甲烷气体含量的升高,金刚石薄膜结晶质量下降,薄膜由微米晶向纳米晶转变。摩擦磨损实验结果显示:3%甲烷浓度条件下制备的金刚石薄膜耐磨性较好,磨损率为2.2×10-7 mm3/mN;5%甲烷浓度条件下制备的金刚石薄膜摩擦系数最低(0.032),磨损率为5.7×10-7 mm3/mN,制备的金刚石薄膜的耐磨损性能相比于碳化硅基底(磨损率为9.89×10-5 mm3/mN)提升了两个数量级,显著提高了碳化硅基底的耐磨性。 相似文献
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We present the fabrication of core-shell-satellite Au@SiO2-Pt nanostructures and demonstrate that LSPR excitation of the core Au nanoparticle can induce plasmon coupling effect to initiate photocatalytic hydrogen generation from decomposition of formic acid. Further studies suggest that the plasmon coupling effect induces a strong local electric field between the Au core and Pt nanoparticles on the SiO2 shell, which enables creation of hot electrons on the non-plasmonic-active Pt nanoparticles to participate hydrogen evolution reaction on the Pt surface. In addition, small SiO2 shell thickness is required in order to obtain a strong plamon coupling effect and achieve efficient photocatalytic activities for hydrogen generation. 相似文献
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Thomas Gelbrich Isabella Meischberger Ulrich J. Griesser 《Acta Crystallographica. Section C, Structural Chemistry》2015,71(3):204-210
Polymorph (Ia) (m.p. 474 K) of the title compound, C12H18N2O3, displays an N—H...O=C hydrogen‐bonded layer structure which contains R66(28) rings connecting six molecules, as well as R22(8) rings linking two molecules. The 3‐connected hydrogen‐bonded net resulting from these interactions has the hcb topology. Form (Ib) (m.p. 471 K) displays N—H...O=C hydrogen‐bonded looped chains in which neighbouring molecules are linked to one another by two different R22(8) rings. Polymorph (Ia) is isostructural with the previously reported form II of 5‐(2‐bromoallyl)‐5‐isopropylbarbituric acid (noctal) and polymorph (Ib) is isostructural with the known crystal structures of four other barbiturates. 相似文献
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Qinghua Guo Minmin Xu Yaxian Yuan Renao Gu Jianlin Yao 《Journal of Raman spectroscopy : JRS》2016,47(5):537-544
Metal nanoparticle dimers with controllable gap distance have attracted considerable attention because of their promising application in plasmonics. Generally, gaps with nanometer or subnanometer dimensions generate localized surface plasmon resonance (LSPR) coupling effect, thus contributing to a strong electromagnetic field for improving surface enhanced Raman scattering (SERS) effect. Here, we developed a facile approach to fabricate Au@SiO2 dimers through the steric hindrance effect, in which the SiO2 shell functioned as a block and a rigid dithiol molecule was employed as linker. The thickness of the SiO2 shell played a critical role in improving the yield of dimers. The dimerization efficiency increased significantly as the shell thickness decreased to ~1 nm. When 1,4‐benzenedithiol was used as linker molecule, the yield of dimers was ~30%. Few dimers were obtained when mecaptobenzonic acid was used as linker. A thicker shell is associated with a low yield of dimer, whereas a thinner shell resulted in the formation of multimers and linear structures. The low number of linker molecules on the exposed area of monodisperse single nanoparticles and the lack of LSPR coupling effect (‘hot spots’) resulted in the disappearance of SERS signals of the linkers. The estimated SERS enhancement factor was about eight fold because of the strong coupling effect in the gap of the dimer with the distance of the dithiol molecular length. From the above results, SERS combined with SEM could be developed into powerful tools for monitoring the formation of dimers and positioning of single dimers. It may aid the control of assembly of Au nanoparticles and in probing key issues about SERS enhancements. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
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We realized a series of experiments to study the physics of laser–plasma interaction in an intensity regime of interest for the novel “Shock Ignition” approach to Inertial Fusion. Experiments were performed at the Prague Asterix Laser System laser in Prague using two laser beams: an “auxiliary” beam, for pre-plasma creation, with intensity around 7?×?1013?W/cm2 (250?ps, 1ω, λ?=?1315?nm) and the “main” beam, up to 1016?W/cm (250?ps, 3ω, λ?=?438?nm), to launch a shock. The main goal of these experiments is to study the process of the formation of a very strong shock and the influence of hot electrons in the generation of very high pressures. The shock produced by the ablation of the plastic layer is studied by shock breakout chronometry. The generation of hot electrons is analyzed by imaging Kα emission. 相似文献
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利用超快光谱技术系统研究了在丁胺包裹的CdSe量子点敏化的TiO2纳米晶薄膜起始时刻界面间电子转移动力学。与之前的报道不同,该实验结果表明:CdSe量子点经过表面修饰后,两相电子注入机制--热电子和冷电子注入得以被证实,即:电子能分别从CdSe量子点导带中高的振动能级和导带底转移到TiO2的导带。该机制详细描绘了电子在纳米界面间转移的图景。进一步研究发现:热电子注入的电子耦合强度(3.6±0.1 meV)比弛豫后的基态电子注入高两个数量级,基于Marcus理论,伴随着0.083 eV的重组能,冷电子注入的耦合强度值为~50 μeV。 相似文献
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Zusammenfassung Der Torsionsversuch eignet sich zur Untersuchung des plastischen Verhaltens von Metallen bei erhöhten Temperaturen, wenn die Fließspannung stark von der Umformgeschwindigkeit abhängt. Aus der gemessenen Drehmoment-Drehwinkel-Kurve wird die Fließkurvek
f
() berechnet. Hierfür wird ein Fließkriterium benötigt, dessen Unsicherheit im allgemeinen größer ist als alle Meßfehler. Diese Unsicherheit geht aber nicht in die berechnete Dehngeschwindigkeitsempfindlichkeit ein, die somit als Hauptergebnis des Versuches anzusehen ist.Um die Bedingungen technischer Warmumformung zu simulieren, wird die Verwendung extrem kurzer Proben (flacher Scheiben) empfohlen, womit sehr hohe Umformgeschwindigkeiten erreicht werden können. Für die Auswertung derartiger Versuche ist die wirksame Länge der kurzen Proben — experimentell oder semiempirisch — zu bestimmen und die Kerbwirkung zu berücksichtigen. Im Gegensatz zur herkömmlichen Vorgehensweise wird empfohlen, die örtliche Spannung und Verzerrung nicht für die Mantelfläche der Probe zu berechnen, sondern für einen kritischen Radialabstand im Innern der Probe, für den die Schiebung von der Kerbwirkung unabhängig ist, so daß sich die zuverlässigsten Werte ergeben.
Summary The torsion test is often used for studying the plastic deformation of metals at elevated temperatures when stress depends strongly on the strain rate. From the measured torque-twisting angle curve, the stress-strain curvek f () has to be calculated. For this purpose a yield criterion has to be used the uncertaintly of which normally exceeds all experimental errors. This uncertaintly, however, does not propagate into the calculated strain rate sensitivity which therefore may be considered as the main result of the torsion test.For simulating the conditions of technical hot forming processes, the use of extremely short test pieces (flat discs) by which very high strain rates can be obtained is recommended. For evaluating the test data the efficient lenght of short specimens has to be determined. In opposition to the conventional procedure of test evaluation, it is recommended not to calculate stress and strain for the surface of the specimen but for a critical radius for which strain is independent of the notch effect so that the most reliable values are obtained.
Mit 5 Abbildungen 相似文献